this is a fantastic, really upbeat song from Late Of The Pier with a nice melody to play along
the whole album is in my opinion flawless, and this is one of the best songs

beginning riff after drums comes in at 00:05
there are variations on this, but its the main idea

e|------12---------12-12------------12---14---12-12-----|
b|---15---15----15------15-------15---15---15------15---|
g|12---------12----------------11-----------------------|  x4
d|------------------------------------------------------|
a|------------------------------------------------------|
e|------------------------------------------------------|

then at a 00:27 this bit that is played under the first riff comes in played on synth

e|-------------------------------------------------------|
b|-------------------------------------------------------|
g|-------------------------------------------------------|
d|-------------------------------------------------------|
a|--------------------------2h3--3--3--3--5--5--5-7--5---|
e|3--3--3--3--3--3-2-3-2-3-----------------------------7-|

e|--------------------------------------------------|
b|--------------------------------------------------|
g|--------------------------------------------------|  and then it goes
d|-----------------------------------------7--7-7---|  back to the first bit
a|-------------------------3h2--2--2--2--5---5-5----|
e|3--3--3--3-2-3--3-2-3-2-3-----------------------5-|  it should fit together

the bit on the xylophone sounds like single note picking of a G chord but i'm not sure

this is whats played when the vocals kick in but you'll have to listen to it for the timing.
oh and the S in the next bit stands for slide

e|------------------------------------------------7----7-|
b|8------7-----------------------------8------10---------|
g|-----------7----4------4s7---4-------------------------|
d|-------------------------------------------------------|
a|-------------------------------------------------------|
e|-------------------------------------------------------|
  lately...

these riffs are repaeted a few times with some variations, but thats it